Electrosynthesis of enaminones directly from methyl ketones and amines with nitromethane as a carbon source

An efficient and mechanistically different method for the electrosynthesis of enaminone directly from methyl ketones, amines and nitromethane was developed. This transition-metal-free method proceeded at room temperature to give a wide array of enaminones in one step, utilizing nitromethane as the c...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-07, Vol.51 (55), p.11108-11111
Main Authors: Xu, Kun, Zhang, Zhenlei, Qian, Peng, Zha, Zhenggen, Wang, Zhiyong
Format: Article
Language:English
Subjects:
Amines
Amines - chemistry
Arrays
Carbon
Electrochemical Techniques
Ketones
Ketones - chemistry
Methane - analogs & derivatives
Methane - chemistry
Molecular Structure
Nitromethane
Nitroparaffins - chemistry
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Summary:An efficient and mechanistically different method for the electrosynthesis of enaminone directly from methyl ketones, amines and nitromethane was developed. This transition-metal-free method proceeded at room temperature to give a wide array of enaminones in one step, utilizing nitromethane as the carbon source.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc02730f