Non-aggregated divanadium pentoxide nanoparticles: A one-step facile synthesis. Morphological, structural, compositional, optical properties and photocatalytic activities

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2014-01, Vol.236, p.82-90
• Main Authors: Abazari, Reza, Sanati, Soheila, Saghatforoush, Lotf Ali
• Format: Article
• Language: English
• Subjects: AOT micelle solution; Differential thermal analysis; Divanadium pentoxide nanoparticles; Optical properties; Photocatalysis; Reverse microemulsion; Scanning electron microscopy; Spectroscopy; Transmission electron microscopy; Uniform spherical shape; Vanadium pentoxide; X-rays
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2013.09.056

Flowchart for chemical processing of the V2O5 NPs synthesized in the reverse microemulsion system. [Display omitted] •Synthesis of perfectly spherical V2O5 nanoparticles stabilized by AOT.•Uniform shape and non-agglomerated of V2O5 NPs made via reverse microemulsion route.•XRD confirmed the orthorhombic phase pure structure of V2O5 nanoparticles.•Highly crystalline & well-dispersed V2O5 nanoparticles were successfully obtained.•The optical properties of these NPs were studied using UV–Vis absorption and PL spectra. In the present paper, pure phase and well-dispersed divanadium pentoxide nanoparticles (V2O5 NPs) with a orthorhombic structure were synthesized via the reverse microemulsion process and using low-cost NH4VO3 as the starting material in the absence of any co-surfactant. The synthetic method is facile, fast, low reaction temperature, environmental friendly, and easy controlled preparation condition. The structure, morphology and optical properties of these particles were characterized by field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), energy dispersive analysis of X-ray (EDAX), X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), differential temperature analysis (DTA), fourier transform infrared spectroscopy (FT-IR), ultraviolet–visible absorption spectroscopy (UV–Vis), and photoluminescence (PL) spectroscopy. The synthesized NPs were found to be fully crystalline and spherical in shape with uniform distribution. The mean crystallite size of the V2O5 NPs was estimated by X-ray powder diffraction pattern, which was in close agreement with the particles size obtained by TEM analysis. Optical properties of the nano-structured V2O5 are also tested and discussed. The band gap value of the V2O5 NPs is about 2.93eV calculated by UV–Vis spectroscopy. Considerable emissions due to oxygen vacancies and band transition of PL peaks were observed. In addition, the photocatalytic activities of these particles were evaluated by photodegradation of toluidine blue O (TBO) dye under visible light irradiation.