GC-FID/MS Profiling of Supercritical CO2 Extracts of Peels from Citrus aurantium, C. sinensis cv. Washington navel, C. sinensis cv. Tarocco and C. sinensis cv. Doppio Sanguigno from Dubrovnik Area (Croatia)

The peels of Citrus aurantium L. and Citrus sinensis Osbeck cultivars from the Dubrovnik region (south Croatia) were extracted by supercritical CO2 at 40°C and 10 MPa at 1.76 kg/h to obtain enriched extracts in comparison with simple pressing of the peels. The extracts were analyzed in detail by gas...

Full description

Saved in:
Bibliographic Details
Published in:Natural product communications 2015-07, Vol.10 (7), p.1315-1318
Main Authors: Jerković, Igor, Družić, Jasmina, Marijanović, Zvonimir, Gugić, Mirko, Jokić, Stela, Roje, Marin
Format: Article
Language:English
Subjects:
Carbon Dioxide
Citrus sinensis - chemistry
Croatia
Fruit - chemistry
Gas Chromatography-Mass Spectrometry
Plant Extracts - chemistry
Online Access:Request full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 1318
container_issue 7
container_start_page 1315
container_title Natural product communications
container_volume 10
creator Jerković, Igor
Družić, Jasmina
Marijanović, Zvonimir
Gugić, Mirko
Jokić, Stela
Roje, Marin
description The peels of Citrus aurantium L. and Citrus sinensis Osbeck cultivars from the Dubrovnik region (south Croatia) were extracted by supercritical CO2 at 40°C and 10 MPa at 1.76 kg/h to obtain enriched extracts in comparison with simple pressing of the peels. The extracts were analyzed in detail by gas chromatography and mass spectrometry (GC-FID/MS). Relevant similarities among the peel oil compositions of C. aurantium and C. sinensis cultivars were found with limonene predominance (up to 54.3%). The principal oxygenated monoterpenes were linalool (3.0%–5.9%), α-terpineol (0.7%–2.4%), linalyl acetate (0.0%–5.0%), geranyl acetate (0.0%-0.4%), (Z)-citral (0.0%–1.8%) and (E)-citral (0.0%–1.9%). Several sesquiterpenes were found with minor percentages. Coumarin derivatives were identified in all the samples among the relevant compounds. Isogeijerin dominated in the peels of C. sinensis cv. Tarocco (15.3%) and C. aurantium (11.2%). Scoparone ranged from 0.1% to 0.5% in all the samples. Bergapten (up to 1.4%), osthole (up to 1.1%) and 7-methoxy-8-(2-formylpropyl)coumarin (up to 1.1%) were found mostly in C. sinensis cv. Doppio Sanguigno. It was possible to indicate a few other differences among the extracts such as higher percentage of linalool, linalyl and geranyl acetates, as well as the abundance of sabinene and isogeijerin in C. aurantium or the occurrence of β-sinensal in C. sinensis cultivars.
doi_str_mv 10.1177/1934578X1501000745
format article
fullrecord <record><control><sourceid>proquest_AFRWT</sourceid><recordid>TN_cdi_proquest_miscellaneous_1717483940</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sage_id>10.1177_1934578X1501000745</sage_id><sourcerecordid>1717483940</sourcerecordid><originalsourceid>FETCH-LOGICAL-p181t-ba168dffc88a1ff4a35e8b01389885912b40187424451a4d9964ca7a95e8687c3</originalsourceid><addsrcrecordid>eNpl0c1qGzEQB_CltDQhzQv0UHRMoWtrvJIlHcM6X5CSgFPa2zIra12lu9JWH6Z9yT5T1zg5-TQD82Nm4F8UH4HOAISYg6oYF_IHcAqUUsH4m-IUOOelYoK_nfoJlHtxUpzH-DwZKiWjTL0vThZLBkArdVr8u6nL67vV_OuaPAbf2d66LfEdWefRBB1sshp7Uj8syNWfFFCnuJ8-GtNH0gU_kNqmkCPBHNAlm4cvpJ6RaJ1x0UaidzPyHePPaWvyjjjcmf5YPGHwWnuCbnM0W_lxtJ6s0W2z3Tp_uLrKbfA7Z3-Ry2CQXNTBY7L4-UPxrsM-mvOXelZ8u756qm_L-4ebu_ryvhxBQipbhKXcdJ2WEqHrGFbcyJZCJZWUXMGiZRSkYAvGOCDbKLVkGgWqiS2l0NVZcXHYOwb_O5uYmsFGbfoenfE5NiBAMFkpRif66YXmdjCbZgx2wPC3ec1gAvMDiLg1zbPPwU2vN0CbfdDNcdDVf3_rl1w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1717483940</pqid></control><display><type>article</type><title>GC-FID/MS Profiling of Supercritical CO2 Extracts of Peels from Citrus aurantium, C. sinensis cv. Washington navel, C. sinensis cv. Tarocco and C. sinensis cv. Doppio Sanguigno from Dubrovnik Area (Croatia)</title><source>SAGE Open Access</source><creator>Jerković, Igor ; Družić, Jasmina ; Marijanović, Zvonimir ; Gugić, Mirko ; Jokić, Stela ; Roje, Marin</creator><creatorcontrib>Jerković, Igor ; Družić, Jasmina ; Marijanović, Zvonimir ; Gugić, Mirko ; Jokić, Stela ; Roje, Marin</creatorcontrib><description>The peels of Citrus aurantium L. and Citrus sinensis Osbeck cultivars from the Dubrovnik region (south Croatia) were extracted by supercritical CO2 at 40°C and 10 MPa at 1.76 kg/h to obtain enriched extracts in comparison with simple pressing of the peels. The extracts were analyzed in detail by gas chromatography and mass spectrometry (GC-FID/MS). Relevant similarities among the peel oil compositions of C. aurantium and C. sinensis cultivars were found with limonene predominance (up to 54.3%). The principal oxygenated monoterpenes were linalool (3.0%–5.9%), α-terpineol (0.7%–2.4%), linalyl acetate (0.0%–5.0%), geranyl acetate (0.0%-0.4%), (Z)-citral (0.0%–1.8%) and (E)-citral (0.0%–1.9%). Several sesquiterpenes were found with minor percentages. Coumarin derivatives were identified in all the samples among the relevant compounds. Isogeijerin dominated in the peels of C. sinensis cv. Tarocco (15.3%) and C. aurantium (11.2%). Scoparone ranged from 0.1% to 0.5% in all the samples. Bergapten (up to 1.4%), osthole (up to 1.1%) and 7-methoxy-8-(2-formylpropyl)coumarin (up to 1.1%) were found mostly in C. sinensis cv. Doppio Sanguigno. It was possible to indicate a few other differences among the extracts such as higher percentage of linalool, linalyl and geranyl acetates, as well as the abundance of sabinene and isogeijerin in C. aurantium or the occurrence of β-sinensal in C. sinensis cultivars.</description><identifier>ISSN: 1934-578X</identifier><identifier>EISSN: 1555-9475</identifier><identifier>DOI: 10.1177/1934578X1501000745</identifier><identifier>PMID: 26411039</identifier><language>eng</language><publisher>Los Angeles, CA: SAGE Publications</publisher><subject>Carbon Dioxide ; Citrus sinensis - chemistry ; Croatia ; Fruit - chemistry ; Gas Chromatography-Mass Spectrometry ; Plant Extracts - chemistry</subject><ispartof>Natural product communications, 2015-07, Vol.10 (7), p.1315-1318</ispartof><rights>2015 SAGE Publications Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://journals.sagepub.com/doi/pdf/10.1177/1934578X1501000745$$EPDF$$P50$$Gsage$$H</linktopdf><linktohtml>$$Uhttps://journals.sagepub.com/doi/10.1177/1934578X1501000745$$EHTML$$P50$$Gsage$$H</linktohtml><link.rule.ids>314,776,780,21945,27830,27901,27902,44921,45309</link.rule.ids><linktorsrc>$$Uhttps://journals.sagepub.com/doi/full/10.1177/1934578X1501000745?utm_source=summon&amp;utm_medium=discovery-provider$$EView_record_in_SAGE_Publications$$FView_record_in_$$GSAGE_Publications</linktorsrc><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26411039$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Jerković, Igor</creatorcontrib><creatorcontrib>Družić, Jasmina</creatorcontrib><creatorcontrib>Marijanović, Zvonimir</creatorcontrib><creatorcontrib>Gugić, Mirko</creatorcontrib><creatorcontrib>Jokić, Stela</creatorcontrib><creatorcontrib>Roje, Marin</creatorcontrib><title>GC-FID/MS Profiling of Supercritical CO2 Extracts of Peels from Citrus aurantium, C. sinensis cv. Washington navel, C. sinensis cv. Tarocco and C. sinensis cv. Doppio Sanguigno from Dubrovnik Area (Croatia)</title><title>Natural product communications</title><addtitle>Nat Prod Commun</addtitle><description>The peels of Citrus aurantium L. and Citrus sinensis Osbeck cultivars from the Dubrovnik region (south Croatia) were extracted by supercritical CO2 at 40°C and 10 MPa at 1.76 kg/h to obtain enriched extracts in comparison with simple pressing of the peels. The extracts were analyzed in detail by gas chromatography and mass spectrometry (GC-FID/MS). Relevant similarities among the peel oil compositions of C. aurantium and C. sinensis cultivars were found with limonene predominance (up to 54.3%). The principal oxygenated monoterpenes were linalool (3.0%–5.9%), α-terpineol (0.7%–2.4%), linalyl acetate (0.0%–5.0%), geranyl acetate (0.0%-0.4%), (Z)-citral (0.0%–1.8%) and (E)-citral (0.0%–1.9%). Several sesquiterpenes were found with minor percentages. Coumarin derivatives were identified in all the samples among the relevant compounds. Isogeijerin dominated in the peels of C. sinensis cv. Tarocco (15.3%) and C. aurantium (11.2%). Scoparone ranged from 0.1% to 0.5% in all the samples. Bergapten (up to 1.4%), osthole (up to 1.1%) and 7-methoxy-8-(2-formylpropyl)coumarin (up to 1.1%) were found mostly in C. sinensis cv. Doppio Sanguigno. It was possible to indicate a few other differences among the extracts such as higher percentage of linalool, linalyl and geranyl acetates, as well as the abundance of sabinene and isogeijerin in C. aurantium or the occurrence of β-sinensal in C. sinensis cultivars.</description><subject>Carbon Dioxide</subject><subject>Citrus sinensis - chemistry</subject><subject>Croatia</subject><subject>Fruit - chemistry</subject><subject>Gas Chromatography-Mass Spectrometry</subject><subject>Plant Extracts - chemistry</subject><issn>1934-578X</issn><issn>1555-9475</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpl0c1qGzEQB_CltDQhzQv0UHRMoWtrvJIlHcM6X5CSgFPa2zIra12lu9JWH6Z9yT5T1zg5-TQD82Nm4F8UH4HOAISYg6oYF_IHcAqUUsH4m-IUOOelYoK_nfoJlHtxUpzH-DwZKiWjTL0vThZLBkArdVr8u6nL67vV_OuaPAbf2d66LfEdWefRBB1sshp7Uj8syNWfFFCnuJ8-GtNH0gU_kNqmkCPBHNAlm4cvpJ6RaJ1x0UaidzPyHePPaWvyjjjcmf5YPGHwWnuCbnM0W_lxtJ6s0W2z3Tp_uLrKbfA7Z3-Ry2CQXNTBY7L4-UPxrsM-mvOXelZ8u756qm_L-4ebu_ryvhxBQipbhKXcdJ2WEqHrGFbcyJZCJZWUXMGiZRSkYAvGOCDbKLVkGgWqiS2l0NVZcXHYOwb_O5uYmsFGbfoenfE5NiBAMFkpRif66YXmdjCbZgx2wPC3ec1gAvMDiLg1zbPPwU2vN0CbfdDNcdDVf3_rl1w</recordid><startdate>201507</startdate><enddate>201507</enddate><creator>Jerković, Igor</creator><creator>Družić, Jasmina</creator><creator>Marijanović, Zvonimir</creator><creator>Gugić, Mirko</creator><creator>Jokić, Stela</creator><creator>Roje, Marin</creator><general>SAGE Publications</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>201507</creationdate><title>GC-FID/MS Profiling of Supercritical CO2 Extracts of Peels from Citrus aurantium, C. sinensis cv. Washington navel, C. sinensis cv. Tarocco and C. sinensis cv. Doppio Sanguigno from Dubrovnik Area (Croatia)</title><author>Jerković, Igor ; Družić, Jasmina ; Marijanović, Zvonimir ; Gugić, Mirko ; Jokić, Stela ; Roje, Marin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p181t-ba168dffc88a1ff4a35e8b01389885912b40187424451a4d9964ca7a95e8687c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Carbon Dioxide</topic><topic>Citrus sinensis - chemistry</topic><topic>Croatia</topic><topic>Fruit - chemistry</topic><topic>Gas Chromatography-Mass Spectrometry</topic><topic>Plant Extracts - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jerković, Igor</creatorcontrib><creatorcontrib>Družić, Jasmina</creatorcontrib><creatorcontrib>Marijanović, Zvonimir</creatorcontrib><creatorcontrib>Gugić, Mirko</creatorcontrib><creatorcontrib>Jokić, Stela</creatorcontrib><creatorcontrib>Roje, Marin</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Natural product communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Jerković, Igor</au><au>Družić, Jasmina</au><au>Marijanović, Zvonimir</au><au>Gugić, Mirko</au><au>Jokić, Stela</au><au>Roje, Marin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>GC-FID/MS Profiling of Supercritical CO2 Extracts of Peels from Citrus aurantium, C. sinensis cv. Washington navel, C. sinensis cv. Tarocco and C. sinensis cv. Doppio Sanguigno from Dubrovnik Area (Croatia)</atitle><jtitle>Natural product communications</jtitle><addtitle>Nat Prod Commun</addtitle><date>2015-07</date><risdate>2015</risdate><volume>10</volume><issue>7</issue><spage>1315</spage><epage>1318</epage><pages>1315-1318</pages><issn>1934-578X</issn><eissn>1555-9475</eissn><abstract>The peels of Citrus aurantium L. and Citrus sinensis Osbeck cultivars from the Dubrovnik region (south Croatia) were extracted by supercritical CO2 at 40°C and 10 MPa at 1.76 kg/h to obtain enriched extracts in comparison with simple pressing of the peels. The extracts were analyzed in detail by gas chromatography and mass spectrometry (GC-FID/MS). Relevant similarities among the peel oil compositions of C. aurantium and C. sinensis cultivars were found with limonene predominance (up to 54.3%). The principal oxygenated monoterpenes were linalool (3.0%–5.9%), α-terpineol (0.7%–2.4%), linalyl acetate (0.0%–5.0%), geranyl acetate (0.0%-0.4%), (Z)-citral (0.0%–1.8%) and (E)-citral (0.0%–1.9%). Several sesquiterpenes were found with minor percentages. Coumarin derivatives were identified in all the samples among the relevant compounds. Isogeijerin dominated in the peels of C. sinensis cv. Tarocco (15.3%) and C. aurantium (11.2%). Scoparone ranged from 0.1% to 0.5% in all the samples. Bergapten (up to 1.4%), osthole (up to 1.1%) and 7-methoxy-8-(2-formylpropyl)coumarin (up to 1.1%) were found mostly in C. sinensis cv. Doppio Sanguigno. It was possible to indicate a few other differences among the extracts such as higher percentage of linalool, linalyl and geranyl acetates, as well as the abundance of sabinene and isogeijerin in C. aurantium or the occurrence of β-sinensal in C. sinensis cultivars.</abstract><cop>Los Angeles, CA</cop><pub>SAGE Publications</pub><pmid>26411039</pmid><doi>10.1177/1934578X1501000745</doi><tpages>4</tpages></addata></record>
fulltext fulltext_linktorsrc
identifier ISSN: 1934-578X
ispartof Natural product communications, 2015-07, Vol.10 (7), p.1315-1318
issn 1934-578X
1555-9475
language eng
recordid cdi_proquest_miscellaneous_1717483940
source SAGE Open Access
subjects Carbon Dioxide
Citrus sinensis - chemistry
Croatia
Fruit - chemistry
Gas Chromatography-Mass Spectrometry
Plant Extracts - chemistry
title GC-FID/MS Profiling of Supercritical CO2 Extracts of Peels from Citrus aurantium, C. sinensis cv. Washington navel, C. sinensis cv. Tarocco and C. sinensis cv. Doppio Sanguigno from Dubrovnik Area (Croatia)
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T14%3A13%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_AFRWT&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=GC-FID/MS%20Profiling%20of%20Supercritical%20CO2%20Extracts%20of%20Peels%20from%20Citrus%20aurantium,%20C.%20sinensis%20cv.%20Washington%20navel,%20C.%20sinensis%20cv.%20Tarocco%20and%20C.%20sinensis%20cv.%20Doppio%20Sanguigno%20from%20Dubrovnik%20Area%20(Croatia)&rft.jtitle=Natural%20product%20communications&rft.au=Jerkovi%C4%87,%20Igor&rft.date=2015-07&rft.volume=10&rft.issue=7&rft.spage=1315&rft.epage=1318&rft.pages=1315-1318&rft.issn=1934-578X&rft.eissn=1555-9475&rft_id=info:doi/10.1177/1934578X1501000745&rft_dat=%3Cproquest_AFRWT%3E1717483940%3C/proquest_AFRWT%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-p181t-ba168dffc88a1ff4a35e8b01389885912b40187424451a4d9964ca7a95e8687c3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1717483940&rft_id=info:pmid/26411039&rft_sage_id=10.1177_1934578X1501000745&rfr_iscdi=true