Heat-set gels formed from easily accessible gelators of a succinamic acid derivative (SAD) and a primary alkyl amine (R-NH2)

• Published in: Soft matter 2015-01, Vol.11 (32), p.6386-6392
• Main Authors: Zhong, Di-Chang, Liao, Lie-Qiang, Wang, Ke-Jun, Liu, Hui-Jin, Luo, Xu-Zhong
• Format: Article
• Language: English
• Subjects: Accessibility; Amines; Amines - chemistry; Carboxylic Acids - chemistry; Derivatives; Dicarboxylic acids; Fatty acids; Fatty Acids - chemistry; Formations; Gels; Gels - chemistry; Hydrogen Bonding; Hydrophobic and Hydrophilic Interactions; Static Electricity; Strategy; Succinates - chemistry; Temperature
• ISSN: 1744-683X; 1744-6848
• DOI: 10.1039/c5sm01305d

Currently, the design and construction of an intelligent stimuli-responsive gel system is still a significant challenge. We present here a new gel system from which the formation of heat-set gels, conventional gels and irreversible heat-set gels can be achieved in aromatic solvents. This gel system is based on two-component gelators containing a succinamic acid derivative (SAD) and a primary alkyl amine (R-NH2). With the increase of temperature to 85 °C, a rarely reported reversible heat-set gel (gel formation with the increase of temperature) is afforded. Upon addition of fatty acids into two-component gelators, a conventional gel (gel formation with the decrease of temperature) is formed. When the fatty acid is replaced with dicarboxylic acid, a new heat-set gel is generated, which is irreversible and thermally super-stable. X-ray diffraction analysis reveals that the formation of a reversible heat-set gel relies on electrostatic interactions, hydrogen bonds, and hydrophobic interactions. These two-component gelators show a perfect gel system for the formation of diverse gels including heat-set gels, conventional gels and irreversible heat-set gels. The tunable strategy demonstrated in this letter may provide a new way for creation of more functional gels in gel science.