Theoretical approach to modelling the low-barrier chemical reactions initiated by pulsed electron beam

A possibility to analyze low-barrier chemical reactions induced by electron beam is proposed within the framework of generalization of classical Kramers approach. A relationship for calculation of chemical reaction rate is received for potential barriers comparable with energy of system. It has been...

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Bibliographic Details
Published in:Journal of physics. Conference series 2014-01, Vol.552 (1), p.12033-5
Main Author: Aktaev, N E
Format: Article
Language:English
Subjects:
Chemical reactions
Dynamic models
Dynamical systems
Dynamics
Electron beams
Mathematical models
Modelling
Physics
Potential barriers
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Summary:A possibility to analyze low-barrier chemical reactions induced by electron beam is proposed within the framework of generalization of classical Kramers approach. A relationship for calculation of chemical reaction rate is received for potential barriers comparable with energy of system. It has been shown that results of our approach agree with results of dynamical modeling within 2% not only in the area of applicability of classical (Kramers) approach but also more widely.
ISSN:1742-6588
1742-6596
DOI:10.1088/1742-6596/552/1/012033