Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks

The assembly of two-dimensional (2D) large channel uranyl-organic polyrotaxane networks as well as structural regulation of uranyl-bearing units using jointed cucurbit[6]uril-based pseudorotaxanes with integral rigidity based on supramolecular inclusion is presented for the first time. This construc...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-08, Vol.51 (60), p.11990-11993
Main Authors: Mei, Lei, Wang, Lin, Yuan, Li-yong, An, Shu-wen, Zhao, Yu-liang, Chai, Zhi-fang, Burns, Peter C, Shi, Wei-qun
Format: Article
Language:English
Subjects:
Assembly
Bridged-Ring Compounds - chemistry
Control
Cyclodextrins - chemistry
Imidazoles - chemistry
Inclusions
Integrals
Models, Molecular
Networks
Poloxamer - chemistry
Rigidity
Rotaxanes - chemistry
Strategy
Two dimensional
Uranium Compounds - chemistry
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Summary:The assembly of two-dimensional (2D) large channel uranyl-organic polyrotaxane networks as well as structural regulation of uranyl-bearing units using jointed cucurbit[6]uril-based pseudorotaxanes with integral rigidity based on supramolecular inclusion is presented for the first time. This construction strategy concerning controlling molecular integral rigidity based on supramolecular inclusion may afford an entirely new methodology for coordination chemistry.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc04409j