Modulation of (non)linear optical properties in tripodal molecules by variation of the peripheral cyano acceptor moieties and the π-spacer

A series of twelve tripodal push-pull molecules with a central triphenylamine donor and peripheral cyano substituted acceptors has been prepared. These molecules possess systematically altered π-linkers as well as cyano acceptors. Based on the experimental properties measured by differential scannin...

Full description

Saved in:
Bibliographic Details
Published in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2015-01, Vol.3 (28), p.7345-7355
Main Authors: Cvejn, D., Michail, E., Polyzos, I., Almonasy, N., Pytela, O., Klikar, M., Mikysek, T., Giannetas, V., Fakis, M., Bureš, F.
Format: Article
Language:English
Subjects:
Acceptors (electronic)
Differential scanning calorimetry
Donors (electronic)
Emission spectroscopy
Mathematical analysis
Modulation
Optical properties
Photon absorption
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A series of twelve tripodal push-pull molecules with a central triphenylamine donor and peripheral cyano substituted acceptors has been prepared. These molecules possess systematically altered π-linkers as well as cyano acceptors. Based on the experimental properties measured by differential scanning calorimetry, electrochemistry, one and two photon absorption/emission spectroscopy, supported by the DFT calculations, thorough structure–property relationships were elucidated.
ISSN:2050-7526
2050-7534
DOI:10.1039/C5TC01293G