Catalytic chemoselective [3+3] cycloadditions of azomethine ylides with quinone monoimides leading to the construction of a dihydrobenzoxazine scaffold

A chemoselective [3+3] cycloaddition of in situ generated azomethine ylides with quinone monoimides has been established, which efficiently led to the construction of dihydrobenzoxazine frameworks with biological relevance, with excellent chemoselectivities and high yields (up to >95 : 5 cr and 9...

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Published in:Chemical communications (Cambridge, England) England), 2015-07, Vol.51 (59), p.11798-11801
Main Authors: Wang, Cong-Shuai, Zhu, Ren-Yi, Zhang, Yu-Chen, Shi, Feng
Format: Article
Language:English
Subjects:
Biological
Catalysis
Catalysts
Construction
Cycloaddition
Quinones
Scaffolds
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creator Wang, Cong-Shuai
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description A chemoselective [3+3] cycloaddition of in situ generated azomethine ylides with quinone monoimides has been established, which efficiently led to the construction of dihydrobenzoxazine frameworks with biological relevance, with excellent chemoselectivities and high yields (up to >95 : 5 cr and 98% yield).
doi_str_mv 10.1039/c5cc03341a
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source Royal Society of Chemistry
subjects Biological
Catalysis
Catalysts
Construction
Cycloaddition
Quinones
Scaffolds
title Catalytic chemoselective [3+3] cycloadditions of azomethine ylides with quinone monoimides leading to the construction of a dihydrobenzoxazine scaffold
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