Chromium nitride coating for large diameter metal-on-polyethylene hip bearings under extreme adverse hip simulator conditions

• Published in: Wear 2015-04, Vol.328-329, p.363-368
• Main Authors: de Villiers, Danielle, Traynor, Alison, Collins, Simon N., Banfield, Sarah, Housden, Jonathan, Shelton, Julia C.
• Format: Article
• Language: English
• Subjects: Bearings; Chromium nitride; Coating; Cobalt; Damage; Joint prostheses; Liners; Polyethylene; Polyethylenes; PVD coatings; Wear; Wear testing
• ISSN: 0043-1648; 1873-2577
• DOI: 10.1016/j.wear.2015.02.060

Large diameter total hip replacements using polyethylene liners have been proposed due to low wear and oxidative stability observed in the latest generation of this material. Concerns exist with large diameter metal bearing surfaces and ceramic heads are generally expensive to manufacture. A ceramic chromium nitride (CrN) coating on a metal head may be an alternative bearing surface, maintaining low polyethylene wear and minimising cobalt release. Vitamin-E blended highly crosslinked polyethylene liners (52mm diameter) paired with electron beam physical vapour deposited (EBPVD) CrN coated and uncoated CoCrMo heads were tested in a hip simulator. Under standard conditions no difference was observed in polyethylene wear rates (9.2 and 9.5mm3/mc) but the coating prevented cobalt release. Alumina particles produced substantial damage on the uncoated heads but did not damage the coated heads. Further testing without abrasive particles increased the polyethylene wear (469mm3/mc) and cobalt release (847ppb/mc) in the uncoated bearings yet remained low in the coated components (13mm3/mc wear, 17ppb/mc cobalt). Additionally, the coating reduced the generation of nanometre sized polyethylene particles by an order of magnitude under all adverse test conditions. This CrN coating may have the potential to reduce clinical wear allowing for large diameter components. •Vitamin-E blended crosslinked polyethylene may be suitable at large hip diameters.•CrN coatings prevent cobalt release from the metal bearing surface.•Adverse conditions increased wear more so in the uncoated bearings.•The coated heads were resistant to aggressive abrasive damage.•Uncoated head damage generated smaller polyethylene wear particles.