Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)3 complexes

The formation of an amidino chelating ligand from the coupling reaction of 1-methylcytosine and nitrile is a new method herein reported for the incorporation of biologically relevant substrates into rhenium(i) tricarbonyl complexes. The reactions are carried out thermally or are microwave assisted.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2015-01, Vol.44 (40), p.17478-17481
Main Authors: Gómez-Iglesias, Patricia, Martín-Alvarez, Jose Miguel, Miguel, Daniel, Villafañe, Fernando
Format: Article
Language:English
Subjects:
Amidines - chemistry
Cytosine - analogs & derivatives
Cytosine - chemistry
Ligands
Luminescent Agents - chemistry
Models, Molecular
Molecular Conformation
Nitriles - chemistry
Organotechnetium Compounds - chemistry
Rhenium - chemistry
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Description
Summary:The formation of an amidino chelating ligand from the coupling reaction of 1-methylcytosine and nitrile is a new method herein reported for the incorporation of biologically relevant substrates into rhenium(i) tricarbonyl complexes. The reactions are carried out thermally or are microwave assisted.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt03221k