End-group differentiating ozonolysis of furocoumarins

Ozonolysis of furocoumarins followed by reductive work-up yields not only common symmetrical dialdehydes, but also o -formylumbelliferones with moderate-to-high yields. Simultaneous formation of both products accounts for the transformation of carbonyl oxides – products of primary ozonide ring openi...

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Bibliographic Details
Published in:RSC advances 2014-01, Vol.4 (106), p.61277-61280
Main Authors: Malakhov, Mikhail V., Dubinnyi, Maxim A., Vlasova, Natalia V., Zgoda, Victor G., Efremov, Roman G., Boldyrev, Ivan A.
Format: Article
Language:English
Subjects:
Carbonyls
Formations
Oxides
Ozonides
Ring opening
Transformations
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Summary:Ozonolysis of furocoumarins followed by reductive work-up yields not only common symmetrical dialdehydes, but also o -formylumbelliferones with moderate-to-high yields. Simultaneous formation of both products accounts for the transformation of carbonyl oxides – products of primary ozonide ring opening.
ISSN:2046-2069
2046-2069
DOI:10.1039/C4RA08106D