Directional self-assembly of rare-earth hydroxocation nanosheets and paradodecatungstate anions

Simply mixing layered rare-earth hydroxide colloidal solutions and paratungstate solution at pH > 7 led to directional self-assembly of rare-earth hydroxide nanosheets and paradodecatungstates. These hybrids exhibit efficient energy transfer from the OMCT band to rare-earth ions in the hydroxide...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2012-12, Vol.41 (46), p.14055-14058
Main Authors: Jeong, Heejin, Lee, Byung-Il, Byeon, Song-Ho
Format: Article
Language:English
Subjects:
Anions
Energy transfer
Hydroxides
Nanocomposites
Nanomaterials
Nanostructure
Rare earth metals
Self assembly
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Summary:Simply mixing layered rare-earth hydroxide colloidal solutions and paratungstate solution at pH > 7 led to directional self-assembly of rare-earth hydroxide nanosheets and paradodecatungstates. These hybrids exhibit efficient energy transfer from the OMCT band to rare-earth ions in the hydroxide layers as well as highly enhanced f-f transitions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt32421k