Dual sensing of fluoride ions by the o-carborane-triarylborane dyad

The o-carborane-triarylborane dyad shows high fluoride ion affinity through the trigonal-planar boron center while degradation to nido-carborane leads to a turn-on fluorescence response toward fluoride.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2013-01, Vol.42 (7), p.2351-2354
Main Authors: Song, Ki Cheol, Kim, Hyungjun, Lee, Kang Mun, Lee, Yoon Sup, Do, Youngkyu, Lee, Min Hyung
Format: Article
Language:English
Subjects:
Affinity
Boranes - chemistry
Boron
Degradation
Detection
Fluorescence
Fluorides
Fluorides - chemistry
Ions - chemistry
Models, Molecular
Molecular Structure
Quantum Theory
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Description
Summary:The o-carborane-triarylborane dyad shows high fluoride ion affinity through the trigonal-planar boron center while degradation to nido-carborane leads to a turn-on fluorescence response toward fluoride.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt32605a