Fluorescent azadipyrrinato zinc(II) complex: hybridisation with a dipyrrinato ligand

We synthesised heteroleptic azadipyrrinato-dipyrrinato hybrid zinc(II) complex 1-Zn-2, by means of the stepwise coordination method. Homoleptic bis(azadipyrrinato)zinc(II) complex 1-Zn-1 was non-fluorescent, whereas 1-Zn-2 exhibited detectable fluorescence from azadipyrrinato ligand 1.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2012-12, Vol.41 (46), p.14035-14037
Main Authors: Sakamoto, Ryota, Kusaka, Shinpei, Kitagawa, Yasutaka, Kishida, Masa-aki, Hayashi, Mikihiro, Takara, Yusuke, Tsuchiya, Mizuho, Kakinuma, Junko, Takeda, Takuma, Hirata, Keisuke, Ogino, Tomoya, Kawahara, Keisuke, Yagi, Toshiki, Ikehira, Shu, Nakamura, Tomoya, Isomura, Mayuko, Toyama, Mikoto, Ichikawa, Saki, Okumura, Mitsutaka, Nishihara, Hiroshi
Format: Article
Language:English
Subjects:
Fluorescence
Ligands
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Summary:We synthesised heteroleptic azadipyrrinato-dipyrrinato hybrid zinc(II) complex 1-Zn-2, by means of the stepwise coordination method. Homoleptic bis(azadipyrrinato)zinc(II) complex 1-Zn-1 was non-fluorescent, whereas 1-Zn-2 exhibited detectable fluorescence from azadipyrrinato ligand 1.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt32039h