Synthesis of Triple-ringed [14]Arene via Dynamic Covalent Chemistry Mechanism in Condensation Reaction of Phenols with m-Benzenedicarbaldehyde

Condensation reaction of 2-methylresorcinol with m-benzenedicarbaldehyde in the presence of HCl as a catalyst in n-propanol at 90 °C for 48 h proceeded via a dynamic covalent chemistry (DCC) mechanism to afford a triple-ringed [14]arene in 52% yield.

Saved in:
Bibliographic Details
Published in:Chemistry letters 2012-07, Vol.41 (7), p.699-701
Main Authors: Seki, Hiroyuki, Kuwabara, Shingo, Kudo, Hiroto, Nishikubo, Tadatomi
Format: Article
Language:English
Subjects:
Catalysts
Condensing
Covalence
Dynamics
Phenols
Synthesis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Condensation reaction of 2-methylresorcinol with m-benzenedicarbaldehyde in the presence of HCl as a catalyst in n-propanol at 90 °C for 48 h proceeded via a dynamic covalent chemistry (DCC) mechanism to afford a triple-ringed [14]arene in 52% yield.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2012.699