Experimental and DFT study on the indium-mediated synthesis of benzophenones via arylstannanes

Experimental results of the solvent-free, indium-promoted reaction of aroyl chlorides with arylstannanes showed a narrow scope; its efficiency depends both on the extent of methylation in the latter and on the nature, number and position of the substituents in the former. With the purpose of explain...

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Bibliographic Details
Published in:RSC advances 2014-01, Vol.4 (90), p.49079-49085
Main Authors: Lo Fiego, Marcos J., Dorn, Viviana B., Badajoz, Mercedes A., Lockhart, María T., Chopa, Alicia B.
Format: Article
Language:English
Subjects:
Chlorides
Methylation
Synthesis
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Summary:Experimental results of the solvent-free, indium-promoted reaction of aroyl chlorides with arylstannanes showed a narrow scope; its efficiency depends both on the extent of methylation in the latter and on the nature, number and position of the substituents in the former. With the purpose of explaining experimental results, a theoretical analysis with DFT methods was performed for a set of selected cases.
ISSN:2046-2069
2046-2069
DOI:10.1039/C4RA07305C