Palladium ketonyl carboxylate complexes - potential models of polynuclear intermediates in olefin oxidation: formation and X-ray structure of Pd sub(6)( mu -Cl) sub(2+x)( mu -CF sub(3)CO sub(2)) sub(4)( mu , Kappa super(2) -CH sub(2)C(O)CMe sub(3)) sub(6-x) (x= 0, 2)

Reactions of Pd sub(4)(NO) sub(4)(CF sub(3)CO sub(2)) sub(4) with olefins were studied, this Pd-cluster was shown to promote the oxidation of olefins into ketones, which were found as ketonyl ligands in complex products of the reaction; 6-nuclear palladium clusters with carboxylate and ketonyl ligan...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2013-01, Vol.42 (5), p.1338-1341
Main Authors: Shishilov, Oleg N, Podobedov, Roman E, Rezinkova, Yaroslavna N, Churakov, Andrei V, Efimenko, Inessa A
Format: Article
Language:English
Subjects:
Carboxylates
Clusters
Ketones
Ligands
Olefins
Oxidation
Palladium
X-rays
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Summary:Reactions of Pd sub(4)(NO) sub(4)(CF sub(3)CO sub(2)) sub(4) with olefins were studied, this Pd-cluster was shown to promote the oxidation of olefins into ketones, which were found as ketonyl ligands in complex products of the reaction; 6-nuclear palladium clusters with carboxylate and ketonyl ligands Pd sub(6)( mu -Cl) sub(x)( mu -CF sub(3)CO sub(2)) sub(4)( mu , Kappa super(2)-CH sub(2)C (O)CMe sub(3) ) sub(6-x) were characterized by XRD analysis.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt31824e