A Novel poly {(2,5-diyl thiophene) (2-Thiophenyl Methine)} from the Acid-Catalyzed Polycondensation of thiophene and thiophene-2-carbanaldehyde

Conjugated poly [(thiophene methine) have been synthesized by a simple method: Condensation of thiophene-2-carbaldehyde with thiophene, catalyzed by Maghnite-H+, which is an exchanged montmorillonite sheet silicate with protons to produce Maghnite-H+ non-toxic cationic catalyst, and characterized by...

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Bibliographic Details
Published in:IOP conference series. Materials Science and Engineering 2012-01, Vol.28 (1), p.12033-9
Main Authors: Belmokhtar, A, Yahiaoui, A, Hachemaoui, A, Sahli, N, Benyoucef, A, Belfedal, A, Belbachir, M
Format: Article
Language:English
Subjects:
Cationic
Condensates
Condensing
Conductors
Exchanging
Montmorillonite
Optical measurement
Semiconductors
Silicates
Thiophenes
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Summary:Conjugated poly [(thiophene methine) have been synthesized by a simple method: Condensation of thiophene-2-carbaldehyde with thiophene, catalyzed by Maghnite-H+, which is an exchanged montmorillonite sheet silicate with protons to produce Maghnite-H+ non-toxic cationic catalyst, and characterized by FT-IR and UV-Vis. The result reveals that the yield of PTTM increase with time and amount of Mag-H. The results obtained with optical measurements and analyzed by different models, show clearly that our material (PTTM) is a good semi-conductor, when the average gap around 5 eV. The effect of the amount of Mag-H+, and the time of polymer was studied.
ISSN:1757-899X
1757-8981
1757-899X
DOI:10.1088/1757-899X/28/1/012033