A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

A new organically-templated vanadium(III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2014-05, Vol.43 (17), p.6304-6307
Main Authors: Aidoudi, Farida H, Downie, Lewis J, Morris, Russell E, A de Vries, Mark, Lightfoot, Philip
Format: Article
Language:English
Subjects:
Antiferromagnetism
Cationic
Distortion
Filing
Fluorides
Frustration
Ground state
Planes
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Summary:A new organically-templated vanadium(III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt00452c