Temperature and solvent effects on polyphenol extraction process from chestnut tree wood

• Published in: Chemical engineering research & design 2011-07, Vol.89 (7), p.857-862
• Main Authors: Gironi, Fausto, Piemonte, Vincenzo
• Format: Article
• Language: English
• Subjects: Adsorption; Applied sciences; Biological and medical sciences; Chemical engineering; Chestnut; Chestnut wood; Equilibrium isotherm; Exact sciences and technology; Extraction; Extraction kinetics; Food engineering; Food industries; Fundamental and applied biological sciences. Psychology; General aspects; Heat and mass transfer. Packings, plates; Liquid phases; Liquid-liquid extraction; Mathematical models; Polyphenols; Solvent extraction; Solvents; Tannins; Wood
• ISSN: 0263-8762
• DOI: 10.1016/j.cherd.2010.11.003

▶ Solvent temperature affects positively the polyphenol extraction from chestnut wood. ▶ Extractable polyphenol content increases by adding ethanol in water solutions. ▶ Both solvent type and temperature affect positively the extraction kinetics of polyphenols. ▶ Extraction rate is controlled by the internal diffusion of polyphenols in wood matrix. Polyphenols are a group of chemical substances found in plants, characterized by the presence of more than one phenol unit or building block per molecule. Polyphenols are generally divided into hydrolysable tannins (gallic acid esters of glucose and other sugars) and phenylpropanoids, such as lignins, flavonoids, and condensed tannins. They are widely found in natural products, nowadays they are extensively used in food and beverage industry and in pharmaceutical and nutraceutical industry for their positive effects on human health. In conventional processes polyphenols are extracted from vegetable material using water as solvent in a temperature range from 40 to 90 °C. The aim of this work is to characterize chestnut tree wood in terms of total extractable polyphenols and assess the temperature and solvent type effects on the polyphenol extraction process. To this end, experimental data on equilibrium distribution of polyphenols between solid and liquid phases for different temperatures (ranging from 60 to 80 °C) and different solvent solutions (water and ethanol–water solutions) are reported. The obtained results have been correlated by means of Freundlich isotherm. Experimental data are also reported about the batch extraction kinetics of polyphenols from solid phase and analysed by a mathematical model to estimate the polyphenol diffusion coefficient inside the chestnut wood particles and the mass transfer coefficient in the liquid phase.