An ultra-microporous organic polymer for high performance carbon dioxide capture and separation

Rational design concepts were used to prepare a novel porous benzimidazole-linked polymer (BILP-101) in a simple one-pot reaction. BILP-101 has exhibited ultra-microporosity (0.54 nm), very high CO2 uptake (∼1 mmol g(-1), 4 wt%, 0.15 bar/298 K) and exceptional CO2/N2 selectivity of 80 (298 K), which...

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Published in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (69), p.13393-13396
Main Authors: Sekizkardes, Ali Kemal, Culp, Jeffrey T, Islamoglu, Timur, Marti, Anne, Hopkinson, David, Myers, Christina, El-Kaderi, Hani M, Nulwala, Hunaid B
Format: Article
Language:English
Subjects:
Carbon capture and storage
Carbon dioxide
Selectivity
Separation
Uptakes
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cited_by cdi_FETCH-LOGICAL-c386t-f05c44c193dc45e92f0bd31a87a1a4a0f831aa0611fc38278a60a178229ea8ef3
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container_title Chemical communications (Cambridge, England)
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creator Sekizkardes, Ali Kemal
Culp, Jeffrey T
Islamoglu, Timur
Marti, Anne
Hopkinson, David
Myers, Christina
El-Kaderi, Hani M
Nulwala, Hunaid B
description Rational design concepts were used to prepare a novel porous benzimidazole-linked polymer (BILP-101) in a simple one-pot reaction. BILP-101 has exhibited ultra-microporosity (0.54 nm), very high CO2 uptake (∼1 mmol g(-1), 4 wt%, 0.15 bar/298 K) and exceptional CO2/N2 selectivity of 80 (298 K), which results in remarkable working capacity and regenerability for CO2 capture applications.
doi_str_mv 10.1039/c5cc04656d
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subjects Carbon capture and storage
Carbon dioxide
Selectivity
Separation
Uptakes
title An ultra-microporous organic polymer for high performance carbon dioxide capture and separation
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