Synthesis and electronic structure of the first cyaphide-alkynyl complexes

The novel complexes trans-[Ru(dppe)2(C≡CR)(C≡P)] (R = CO2Me, C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis studies.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2014-06, Vol.43 (24), p.9004-9007
Main Authors: Trathen, Nicola, Leech, Matthew C, Crossley, Ian R, Greenacre, Victoria K, Roe, S Mark
Format: Article
Language:English
Subjects:
Electronic structure
Synthesis
X-rays
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Summary:The novel complexes trans-[Ru(dppe)2(C≡CR)(C≡P)] (R = CO2Me, C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis studies.
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt01108b