Tetra‑n‑butylammonium Iodide Catalyzed C–H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone

Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C–H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.

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Bibliographic Details
Published in:Organic letters 2015-11, Vol.17 (21), p.5212-5215
Main Authors: Shinomoto, Yukino, Yoshimura, Akira, Shimizu, Hisato, Yamazaki, Mutsumi, Zhdankin, Viktor V, Saito, Akio
Format: Article
Language:English
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Summary:Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C–H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.5b02543