Palladium/NHC-catalyzed tandem benzylic oxidation/oxidative esterification of benzylic alcohols with phenols

A palladium/NHC-catalyzed tandem benzylic oxidation/oxidative esterification of benzylic alcohols with phenols to access aryl benzoate derivatives is described. The procedure tolerates a series of functional groups, such as methoxy, nitro, cyano, chloro, fluoro and bromo groups. Thus, it represents...

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Bibliographic Details
Published in:Tetrahedron 2011-08, Vol.67 (33), p.5878-5882
Main Authors: Luo, Fang, Pan, Changduo, Cheng, Jiang, Chen, Fan
Format: Article
Language:English
Subjects:
Alcohols
Aromatic compounds
Benzoates
Chemistry
Derivatives
Esterification
Exact sciences and technology
Noncondensed benzenic compounds
Organic chemistry
Oxidation
Palladium
Phenols
Preparations and properties
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Summary:A palladium/NHC-catalyzed tandem benzylic oxidation/oxidative esterification of benzylic alcohols with phenols to access aryl benzoate derivatives is described. The procedure tolerates a series of functional groups, such as methoxy, nitro, cyano, chloro, fluoro and bromo groups. Thus, it represents a practically alternative method to access aryl benzoate derivatives. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2011.06.060