Synthesis and solid state structure of pyridyl diboroxines linked by a chiral spacer analogous to Tröger’s base

[Display omitted] Pyridyl-assisted templating of phenyl boronic acid has been utilised to link two remote boroxines via a chiral spacer. The chiral spacer is a carbocyclic analogue of Tröger’s base and contains a unique chiral cavity, and the flanking boroxine units have been shown, by single crysta...

Full description

Saved in:
Bibliographic Details
Published in:Tetrahedron letters 2015-01, Vol.56 (2), p.346-349
Main Authors: Elsegood, Mark R.J., Kimber, Marc C.
Format: Article
Language:English
Subjects:
Analogue
Boronic acid
Boroxine
Chiral cleft
Holes
Links
Phenyls
Pyridyl
Self-assembly
Spacers
Synthesis (chemistry)
Tetrahedrons
X-rays
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:[Display omitted] Pyridyl-assisted templating of phenyl boronic acid has been utilised to link two remote boroxines via a chiral spacer. The chiral spacer is a carbocyclic analogue of Tröger’s base and contains a unique chiral cavity, and the flanking boroxine units have been shown, by single crystal X-ray analysis, to extend the size and shape of this cavity.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2014.11.094