Intramolecular Pauson–Khand reaction catalyzed by oxime-derived palladacycles

Oxime-derived palladacycles were successfully applied as a novel class of catalysts in the intramolecular Pauson–Khand reactions. Allylpropargyl ethers and allylpropargyl amines can be efficiently converted to the cyclopentenone products with good to excellent yields.

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Bibliographic Details
Published in:Tetrahedron letters 2012-02, Vol.53 (5), p.589-592
Main Authors: Wang, Xue-Rui, Lu, Fu-Hua, Song, Yang, Lu, Zhong-Lin
Format: Article
Language:English
Subjects:
Amines
Catalysis
Catalysts
Enynes
Ethers
Oxime-palladacycles
Pauson-Khand reactions
Tetrahedrons
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Description
Summary:Oxime-derived palladacycles were successfully applied as a novel class of catalysts in the intramolecular Pauson–Khand reactions. Allylpropargyl ethers and allylpropargyl amines can be efficiently converted to the cyclopentenone products with good to excellent yields.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2011.11.106