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Effect of NaCl on the conversion of cellulose to glucose and levulinic acid via solid supported acid catalysis
Cellulose is hydrolyzed to glucose, which is further converted to levulinic acid in the presence of Nafion, as a surface supported acid catalyst. The addition of simple alkali metal halide salts, including NaCl, provides significant enhancement to the yield. The catalyst can be recycled suggesting p...
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Published in: | Tetrahedron letters 2011-11, Vol.52 (44), p.5891-5893 |
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container_issue | 44 |
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creator | Potvin, Joshua Sorlien, Erin Hegner, Jessica DeBoef, Brenton Lucht, Brett L. |
description | Cellulose is hydrolyzed to glucose, which is further converted to levulinic acid in the presence of Nafion, as a surface supported acid catalyst. The addition of simple alkali metal halide salts, including NaCl, provides significant enhancement to the yield. The catalyst can be recycled suggesting possible extension into a continuous flow reactor for the synthesis of the biofuel precursors. |
doi_str_mv | 10.1016/j.tetlet.2011.09.013 |
format | article |
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The addition of simple alkali metal halide salts, including NaCl, provides significant enhancement to the yield. The catalyst can be recycled suggesting possible extension into a continuous flow reactor for the synthesis of the biofuel precursors.</description><subject>Applied sciences</subject><subject>Biofuel production</subject><subject>Biofuels</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides</subject><subject>Carbohydrates. Nucleosides and nucleotides</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalysts: preparations and properties</subject><subject>Cellulose</subject><subject>Chemical engineering</subject><subject>Chemistry</subject><subject>Conversion</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. 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C atoms, dissacharides and oligosaccharides</topic><topic>Carbohydrates. Nucleosides and nucleotides</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalysts: preparations and properties</topic><topic>Cellulose</topic><topic>Chemical engineering</topic><topic>Chemistry</topic><topic>Conversion</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>General and physical chemistry</topic><topic>Glucose</topic><topic>Industrial applications and implications. Economical aspects</topic><topic>Nafion</topic><topic>Organic chemistry</topic><topic>Precursors</topic><topic>Preparations and properties</topic><topic>Reactors</topic><topic>Recycled</topic><topic>Solid-supported catalyst</topic><topic>Tetrahedrons</topic><topic>Theory of reactions, general kinetics. Catalysis. 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subjects | Applied sciences Biofuel production Biofuels Biological and medical sciences Biotechnology Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Catalysis Catalysts Catalysts: preparations and properties Cellulose Chemical engineering Chemistry Conversion Energy Exact sciences and technology Fundamental and applied biological sciences. Psychology General and physical chemistry Glucose Industrial applications and implications. Economical aspects Nafion Organic chemistry Precursors Preparations and properties Reactors Recycled Solid-supported catalyst Tetrahedrons Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
title | Effect of NaCl on the conversion of cellulose to glucose and levulinic acid via solid supported acid catalysis |
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