Reactions of Molybdenum Hydrides with Organochlorosilanes

Reactions of molybdenum hydrides containing polydentate phosphinoalkylsilyl ligands with a number of chlorosilanes have been investigated; this has led to the discovery of a novel type of a dechlorinative Si-Si coupling reaction.

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Bibliographic Details
Published in:Chemistry letters 2014-07, Vol.43 (7), p.1005-1005
Main Authors: Asaeda, Takahiro, Yeon Lee, Joo, Watanabe, Kyosuke, Minato, Makoto
Format: Article
Language:English
Subjects:
Chemical reactions
Chlorosilanes
Dechlorination
Hydrides
Ligands
Molybdenum
Online Access:Get full text
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Description
Summary:Reactions of molybdenum hydrides containing polydentate phosphinoalkylsilyl ligands with a number of chlorosilanes have been investigated; this has led to the discovery of a novel type of a dechlorinative Si-Si coupling reaction.
ISSN:0366-7022
1348-0715