Oxorhenium-catalyzed deoxydehydration of glycols and epoxides

The conversion of renewable cellulosic biomass into hydrocarbons has attracted significant attention with a growing demand of sustainability. MeReO3 catalyzes the deoxydehydration (DODH) of glycols and epoxides to alkenes by primary and secondary alcohols (5-nonanol, 3-octanol, 1-butanol) in the ben...

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Bibliographic Details
Published in:Tetrahedron letters 2014-07, Vol.55 (30), p.4178-4180
Main Authors: Davis, Jacqkis, Srivastava, Radhey S.
Format: Article
Language:English
Subjects:
Alkenes
Benzene
Conversion
Demand
Deoxydehydration (DODH)
Epoxides
Glycols
Hydrocarbons
Oxorhenium (CH3ReO3)
Primary alcohol
Secondary alcohols
Solvents
Tetrahedrons
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Summary:The conversion of renewable cellulosic biomass into hydrocarbons has attracted significant attention with a growing demand of sustainability. MeReO3 catalyzes the deoxydehydration (DODH) of glycols and epoxides to alkenes by primary and secondary alcohols (5-nonanol, 3-octanol, 1-butanol) in the benzene solvent. The product yield range from moderate to excellent.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2014.05.044