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A N-heterocyclic carbene (NHC) platinum complex as pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines and oxidative amination of ω-alkenic amines
A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields. The substrate scope...
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| Published in: | Tetrahedron 2012-04, Vol.68 (15), p.3172-3178 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c360t-e9d1e063e906d02b368e1218fc561536f2beaa9db5866b4c99e6835c7922c1d03 |
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| cites | cdi_FETCH-LOGICAL-c360t-e9d1e063e906d02b368e1218fc561536f2beaa9db5866b4c99e6835c7922c1d03 |
| container_end_page | 3178 |
| container_issue | 15 |
| container_start_page | 3172 |
| container_title | Tetrahedron |
| container_volume | 68 |
| creator | Zhang, Rui Xu, Qin Mei, Liang-yong Li, Sheng-ke Shi, Min |
| description | A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields. The substrate scope has been carefully examined and the plausible reaction mechanism has been also proposed.
[Display omitted] A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields. |
| doi_str_mv | 10.1016/j.tet.2012.02.060 |
| format | article |
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[Display omitted] A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields.</description><identifier>ISSN: 0040-4020</identifier><identifier>EISSN: 1464-5416</identifier><identifier>DOI: 10.1016/j.tet.2012.02.060</identifier><identifier>CODEN: TETRAB</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Alkylamines ; Amines ; Carbenes ; Catalysis ; Catalysts: preparations and properties ; Chemistry ; Exact sciences and technology ; General and physical chemistry ; Heterocyclic compounds ; Heterocyclic compounds with only one n hetero atom and condensed derivatives ; Intramolecular hydroamination ; Kinetics and mechanisms ; N-Heterocyclic carbene ; Olefins ; Organic chemistry ; Platinum ; Platinum complex ; Preparations and properties ; Reaction mechanisms ; Reactivity and mechanisms ; Tetrahedrons ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Tetrahedron, 2012-04, Vol.68 (15), p.3172-3178</ispartof><rights>2012 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c360t-e9d1e063e906d02b368e1218fc561536f2beaa9db5866b4c99e6835c7922c1d03</citedby><cites>FETCH-LOGICAL-c360t-e9d1e063e906d02b368e1218fc561536f2beaa9db5866b4c99e6835c7922c1d03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25669907$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Rui</creatorcontrib><creatorcontrib>Xu, Qin</creatorcontrib><creatorcontrib>Mei, Liang-yong</creatorcontrib><creatorcontrib>Li, Sheng-ke</creatorcontrib><creatorcontrib>Shi, Min</creatorcontrib><title>A N-heterocyclic carbene (NHC) platinum complex as pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines and oxidative amination of ω-alkenic amines</title><title>Tetrahedron</title><description>A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields. The substrate scope has been carefully examined and the plausible reaction mechanism has been also proposed.
[Display omitted] A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields.</description><subject>Alkylamines</subject><subject>Amines</subject><subject>Carbenes</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Heterocyclic compounds</subject><subject>Heterocyclic compounds with only one n hetero atom and condensed derivatives</subject><subject>Intramolecular hydroamination</subject><subject>Kinetics and mechanisms</subject><subject>N-Heterocyclic carbene</subject><subject>Olefins</subject><subject>Organic chemistry</subject><subject>Platinum</subject><subject>Platinum complex</subject><subject>Preparations and properties</subject><subject>Reaction mechanisms</subject><subject>Reactivity and mechanisms</subject><subject>Tetrahedrons</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Rui</creatorcontrib><creatorcontrib>Xu, Qin</creatorcontrib><creatorcontrib>Mei, Liang-yong</creatorcontrib><creatorcontrib>Li, Sheng-ke</creatorcontrib><creatorcontrib>Shi, Min</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Tetrahedron</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Rui</au><au>Xu, Qin</au><au>Mei, Liang-yong</au><au>Li, Sheng-ke</au><au>Shi, Min</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A N-heterocyclic carbene (NHC) platinum complex as pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines and oxidative amination of ω-alkenic amines</atitle><jtitle>Tetrahedron</jtitle><date>2012-04-15</date><risdate>2012</risdate><volume>68</volume><issue>15</issue><spage>3172</spage><epage>3178</epage><pages>3172-3178</pages><issn>0040-4020</issn><eissn>1464-5416</eissn><coden>TETRAB</coden><abstract>A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields. The substrate scope has been carefully examined and the plausible reaction mechanism has been also proposed.
[Display omitted] A N-heterocyclic carbene (NHC) platinum complex 3 prepared from BINAM was found to be a highly effective pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines to give the corresponding intramolecular hydroamination products in excellent yields.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.tet.2012.02.060</doi><tpages>7</tpages></addata></record> |
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| ispartof | Tetrahedron, 2012-04, Vol.68 (15), p.3172-3178 |
| issn | 0040-4020 1464-5416 |
| language | eng |
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| source | ScienceDirect Freedom Collection 2022-2024 |
| subjects | Alkylamines Amines Carbenes Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Intramolecular hydroamination Kinetics and mechanisms N-Heterocyclic carbene Olefins Organic chemistry Platinum Platinum complex Preparations and properties Reaction mechanisms Reactivity and mechanisms Tetrahedrons Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | A N-heterocyclic carbene (NHC) platinum complex as pre-catalyst for the intramolecular hydroamination of olefins with secondary alkylamines and oxidative amination of ω-alkenic amines |
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