Nano-copper catalyzed three-component reaction to construct 1,4-substituted 1,2,3-triazoles

Three-component reaction of alkyl halides, sodium azide with terminal alkynes can be catalyzed by nano-copper particles under ambient conditions. A series of 1,4-disubstituted-1,2,3-triazoles were obtained regioselectively by this one-pot strategy. Nano copper can be reused at least three times with...

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Published in:Tetrahedron letters 2014-04, Vol.55 (14), p.2312-2316
Main Authors: Huang, Lina, Liu, Wei, Wu, Juncheng, Fu, Ying, Wang, Kehu, Huo, Congde, Du, Zhengyin
Format: Article
Language:English
Subjects:
Alkynes
Click chemistry
Copper nanoparticles
Cycloaddition
Deactivation
HALIDES
MICROSTRUCTURES
Multicomponent reaction
Nanostructure
Phenylacetylene
Sodium azides
Strategy
Terminals
Tetrahedrons
TRIAZOLE
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cited_by cdi_FETCH-LOGICAL-c339t-cad19de421474fb142718342b4c8af9e031902717fa72bdaedd31a8c6ee52c293
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container_issue 14
container_start_page 2312
container_title Tetrahedron letters
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creator Huang, Lina
Liu, Wei
Wu, Juncheng
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Wang, Kehu
Huo, Congde
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description Three-component reaction of alkyl halides, sodium azide with terminal alkynes can be catalyzed by nano-copper particles under ambient conditions. A series of 1,4-disubstituted-1,2,3-triazoles were obtained regioselectively by this one-pot strategy. Nano copper can be reused at least three times without significant deactivation.
doi_str_mv 10.1016/j.tetlet.2014.02.114
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source ScienceDirect Freedom Collection
subjects Alkynes
Click chemistry
Copper nanoparticles
Cycloaddition
Deactivation
HALIDES
MICROSTRUCTURES
Multicomponent reaction
Nanostructure
Phenylacetylene
Sodium azides
Strategy
Terminals
Tetrahedrons
TRIAZOLE
title Nano-copper catalyzed three-component reaction to construct 1,4-substituted 1,2,3-triazoles
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