Total synthesis of antifungal gamahonolide A

[Display omitted] The first stereoselective total synthesis of gamahonolide A (1) has been accomplished using aminoxylation, Keck allylation, and ring-closing metathesis (RCM) reactions as key steps.

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Bibliographic Details
Published in:Tetrahedron letters 2014-05, Vol.55 (21), p.3227-3228
Main Authors: Sabitha, Gowravaram, Reddy, K. Purushotham, Reddy, S. Purushotham, Yadav, J.S.
Format: Article
Language:English
Subjects:
Allyl compounds
Aminoxylation
Antifungal
Chemical reactions
Decomposition reactions
Keck allylation
Metathesis
Natural product
RCM
Ring-closing metathesis
Synthesis (chemistry)
Tetrahedrons
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Description
Summary:[Display omitted] The first stereoselective total synthesis of gamahonolide A (1) has been accomplished using aminoxylation, Keck allylation, and ring-closing metathesis (RCM) reactions as key steps.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2014.04.026