ipso-Nitrosation of arylboronic acids with chlorotrimethylsilane and sodium nitrite

Nitroso compounds are versatile reagents in synthetic organic chemistry. Herein, we disclose a feasible protocol for the ipso-nitrosation of aryl boronic acids using chlorotrimethylsilane–sodium nitrite unison as nitrosation reagent system.

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Published in:Tetrahedron letters 2014-03, Vol.55 (12), p.1975-1978
Main Authors: Prakash, G.K. Surya, Gurung, Laxman, Schmid, Philipp Christoph, Wang, Fang, Thomas, Tisa Elizabeth, Panja, Chiradeep, Mathew, Thomas, Olah, George A.
Format: Article
Language:English
Subjects:
Aromatic compounds
Boronic acids
Chlorotrimethylsilane
ipso-Nitrosation
Nitrites
Nitroso compounds
Nitrosoarenes
Organic chemistry
Regioselectivity
Sodium nitrite
Tetrahedrons
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cited_by cdi_FETCH-LOGICAL-c339t-145e3d4f3ca6cb7d643121b70298da402cf268972326fb22740fe95505acb5ac3
cites cdi_FETCH-LOGICAL-c339t-145e3d4f3ca6cb7d643121b70298da402cf268972326fb22740fe95505acb5ac3
container_end_page 1978
container_issue 12
container_start_page 1975
container_title Tetrahedron letters
container_volume 55
creator Prakash, G.K. Surya
Gurung, Laxman
Schmid, Philipp Christoph
Wang, Fang
Thomas, Tisa Elizabeth
Panja, Chiradeep
Mathew, Thomas
Olah, George A.
description Nitroso compounds are versatile reagents in synthetic organic chemistry. Herein, we disclose a feasible protocol for the ipso-nitrosation of aryl boronic acids using chlorotrimethylsilane–sodium nitrite unison as nitrosation reagent system.
doi_str_mv 10.1016/j.tetlet.2014.01.138
format article
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source Elsevier
subjects Aromatic compounds
Boronic acids
Chlorotrimethylsilane
ipso-Nitrosation
Nitrites
Nitroso compounds
Nitrosoarenes
Organic chemistry
Regioselectivity
Sodium nitrite
Tetrahedrons
title ipso-Nitrosation of arylboronic acids with chlorotrimethylsilane and sodium nitrite
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