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Oxidation of benzyl alcohols, benzyl halides, and alkylbenzenes with oxone

Oxidation of benzyl alcohols, benzyl halides, and alkylbenzenes to their corresponding oxidation products has been shown to be accomplished directly with oxone. The methodology that involves mere stirring/heating of the reactants and oxone in acetonitrile/water (1:1, v/v) is simple and practical, bu...

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Bibliographic Details
Published in:Tetrahedron 2012-11, Vol.68 (47), p.9763-9768
Main Authors: Parida, Keshaba Nanda, Jhulki, Samik, Mandal, Susovan, Moorthy, Jarugu Narasimha
Format: Article
Language:English
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Summary:Oxidation of benzyl alcohols, benzyl halides, and alkylbenzenes to their corresponding oxidation products has been shown to be accomplished directly with oxone. The methodology that involves mere stirring/heating of the reactants and oxone in acetonitrile/water (1:1, v/v) is simple and practical, but is limited to substrates that do not contain sensitive functionalities and heteroaromatic rings. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2012.09.028