A catalyst-free NaH insertion/Mannich-type reaction cascade of I--nitrodiazoesters

A catalyst-free NaH insertion/Mannich-type reaction cascade of I--nitrodiazoesters with anilines has been developed to afford a variety of I--amino-I--aryl esters in 60a83% yields and under mild reaction conditions (23 or 40 degree C).

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Published in:Tetrahedron letters 2013-08, Vol.54 (32), p.4159-4163
Main Authors: Yang, Ting, Zhuang, Hao, Lin, Xichen, Xiang, Jia-Ning, Elliott, John, Liu, Lianghui, Ren, Feng
Format: Article
Language:English
Subjects:
Aniline
Cascades
Catalysts
Esters
Insertion
Tetrahedrons
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container_end_page 4163
container_issue 32
container_start_page 4159
container_title Tetrahedron letters
container_volume 54
creator Yang, Ting
Zhuang, Hao
Lin, Xichen
Xiang, Jia-Ning
Elliott, John
Liu, Lianghui
Ren, Feng
description A catalyst-free NaH insertion/Mannich-type reaction cascade of I--nitrodiazoesters with anilines has been developed to afford a variety of I--amino-I--aryl esters in 60a83% yields and under mild reaction conditions (23 or 40 degree C).
doi_str_mv 10.1016/j.tetlet.2013.05.131
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subjects Aniline
Cascades
Catalysts
Esters
Insertion
Tetrahedrons
title A catalyst-free NaH insertion/Mannich-type reaction cascade of I--nitrodiazoesters
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