Solvent-free synthesis of new metal phosphate-oxalates: influence of different metal ions on the framework structures

A series of new metal phosphate-oxalates were synthesized under solvent-free conditions. These compounds display interesting open-framework structures with mmt, ins, fsd, and hcb topologies, respectively. The extra-large 20-ring channel, nanobelt-like inorganic skeleton, and the use of cadmium ions...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2015-08, Vol.44 (30), p.13485-13489
Main Authors: Luan, Lindong, Yang, Meng, Bian, Yixuan, Lin, Zhien, Huang, Hui
Format: Article
Language:English
Subjects:
Cadmium
Cations
Channels
Metal ions
Nanostructure
Synthesis
Topology
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Summary:A series of new metal phosphate-oxalates were synthesized under solvent-free conditions. These compounds display interesting open-framework structures with mmt, ins, fsd, and hcb topologies, respectively. The extra-large 20-ring channel, nanobelt-like inorganic skeleton, and the use of cadmium ions as framework cations are unprecedented in metal phosphate-oxalate structures.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt01613d