Sonochemical Synthesis of Bismuth(III) Nano Coordination Compound and Direct Synthesis of Bi sub(2) O sub(3) Nanoparticles from a Bismuth(III) Nano Coordination Compound Precursor

A new coordination Compound [Bi(L)(NO sub(3)) sub(2)(ONO sub(2))(CH sub(3)O H)] (1) [L: C sub(5)H sub(4)NCH=NNHCONC sub(5)H sub(4)] has been synthesized by the reaction of Bismuth(III) bromide with the ligand pyridine-2-carbaldehyde isoniazid and characterized by elemental analysis, FT-IR spectrosco...

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Bibliographic Details
Published in:Journal of inorganic and organometallic polymers and materials 2015-09, Vol.25 (5), p.1226-1232
Main Authors: Roodsari, Majid Sadeghi, Shaabani, Behrouz, Mirtamizdoust, Babak, Dusek, Michal, Fejfarova, Karla
Format: Article
Language:English
Subjects:
Coordination compounds
Diffraction
Nanostructure
Oxygen atoms
Scanning electron microscopy
Spectroscopy
Synthesis
X-rays
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Summary:A new coordination Compound [Bi(L)(NO sub(3)) sub(2)(ONO sub(2))(CH sub(3)O H)] (1) [L: C sub(5)H sub(4)NCH=NNHCONC sub(5)H sub(4)] has been synthesized by the reaction of Bismuth(III) bromide with the ligand pyridine-2-carbaldehyde isoniazid and characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction. Single crystal X-ray diffraction reveals that the compound 1 is mononuclear complex, contains Bismuth(III) in a distorted tricapped trigonal prismatic geometry environment of NNO donors of Schiff base ligand, five oxygen atoms of Nitrate molecules and one oxygen atom of methanol molecule. We also synthesized a nano form of the compound 1 by the sonochemical method and characterized it by elemental analysis, scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and IR spectroscopy. The delta -Bi sub(2)O sub(3) nano-particle was obtained by calcinations of the nano compound 1 at 500 super(o)C under air atmosphere and was characterized by SEM and XRD.
ISSN:1574-1443
1574-1451
DOI:10.1007/s10904-015-0231-4