Extreme trace elements fractionation in Cenozoic nephelinites and phonolites from the Moroccan Anti-Atlas (Eastern Saghro)

• Published in: Lithos 2014-12, Vol.210-211, p.69-88
• Main Authors: Berger, Julien, Ennih, Nasser, Liégeois, Jean-Paul
• Format: Article
• Language: English
• Subjects: Circum-Mediterranean volcanism; Intraplate magmatism; Metasomatism; Nb/Ta and Zr/Hf fractionation; Peralkaline differentiation
• ISSN: 0024-4937; 1872-6143
• DOI: 10.1016/j.lithos.2014.09.018

Nephelinites and phonolites from the Moroccan Anti-Atlas form a cogenetic series of volcanic rocks linked by a fractional crystallization process and showing continuous evolutionary trends for trace-elements. According to partial melting calculations, minor element data in olivine and review of published experimental studies, the most primitive nephelinites are low degree (~2%) partial melts from a carbonated LREE-rich spinel lherzolite. Sr–Nd–Pb isotopic compositions indicate the participation of both DM and HIMU end-members in the mantle source of nephelinites; the HIMU component is here interpreted as a relic of the shallow metasomatized Pan-African mantle. The phonolites show similar isotopic composition except for slightly more radiogenic Sr isotopic values. Fractional crystallization calculations were performed using trace-element mineral/bulk rock coefficients determined with new LA-ICP-MS data on minerals together with published equilibrium partition coefficients. The decrease of LREE, Sr and Ba with increasing differentiation is explained by fractionation of large amounts of apatite. Th, Nb and Zr display a behavior of very incompatible elements, reaching extreme concentration in most differentiated phonolites. Ta, Hf and MREE by contrast are characterized by a moderately incompatible to compatible behavior during differentiation. Fractionation of small amount of titanite, in which Ta, Hf and MREE are highly compatible compared to Nb, Zr and LREE (DNb/DTa: 2, DZr/DHf: 1.5 for titanite/phonolite ratios), explains the observed increase in Nb/Ta and Zr/Hf ratios with increasing silica content, from 18 and 40 in nephelinites to 70 and 80 in phonolites, respectively. Clinopyroxene also contributed to the fractionation of Hf from Zr in the very first steps of crystallization. The low values of Nb/Ta and Zr/Hf ratios observed in the two most differentiated Si-rich phonolites are probably a consequence of late stage segregation of volatile-rich agpaitic assemblages in the underlying magma chamber. Two phonolites with extreme Sr contents plot outside fractionation trends, as a result of the remelting of previously crystallized nephelinitic rocks in depth. •Nephelinites from Saghro are low degree partial melts from a carbonated lherzolite.•Fractional crystallization leaded to extreme enrichment of very incompatible elements.•Fractionation of titanite-bearing assemblages modified the Zr/Hf and Nb/Ta ratios.•Asthenospheric upwelling and tectonic reactivation