Direct heptafluoroisopropylation of arylboronic acids via hexafluoropropene (HFP)

A novel and straightforward strategy for heptafluoroisopropylation of arylboronic acids at room temperature has been developed. This method, directly using commercial available hexafluoropropene (HFP) as the starting material, provides a new way to synthesize a variety of synthetically useful heptaf...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (4), p.796-799
Main Authors: Li, Yajun, Wang, Xiaojun, Guo, Yuwei, Zhu, Zhentong, Wu, Yongming, Gong, Yuefa
Format: Article
Language:English
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Summary:A novel and straightforward strategy for heptafluoroisopropylation of arylboronic acids at room temperature has been developed. This method, directly using commercial available hexafluoropropene (HFP) as the starting material, provides a new way to synthesize a variety of synthetically useful heptafluoroisopropylated arenes.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc07616a