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Preparing the Way for Doping Wurtzite Silicon Nanowires while Retaining the Phase

It is demonstrated that boron-doped nanowires have predominantly long-term stable wurtzite phase while the majority of phosphorus-doped ones present diamond phase. A simplified model based on the different solubility of boron and phosphorus in gold is proposed to explain their diverse effectiveness...

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Published in:	Nano letters 2013-12, Vol.13 (12), p.5900-5906
Main Authors:	Fabbri, Filippo, Rotunno, Enzo, Lazzarini, Laura, Cavalcoli, Daniela, Castaldini, Antonio, Fukata, Naoki, Sato, Keisuke, Salviati, Giancarlo, Cavallini, Anna
Format:	Article
Language:	English
Subjects:	Applied sciences Boron - chemistry Cross-disciplinary physics: materials science rheology Devices Diamonds Emission Energy Exact sciences and technology Fullerenes and related materials diamonds, graphite Gold - chemistry Humans Materials science Nanocrystalline materials Nanoscale materials and structures: fabrication and characterization Nanostructure Nanowires Nanowires - chemistry Natural energy Phosphorus - chemistry Photovoltaic conversion Physics Quantum wires Silicon Silicon - chemistry Solar cells. Photoelectrochemical cells Solar Energy Solubility Specific materials Wurtzite
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creator	Fabbri, Filippo Rotunno, Enzo Lazzarini, Laura Cavalcoli, Daniela Castaldini, Antonio Fukata, Naoki Sato, Keisuke Salviati, Giancarlo Cavallini, Anna
description	It is demonstrated that boron-doped nanowires have predominantly long-term stable wurtzite phase while the majority of phosphorus-doped ones present diamond phase. A simplified model based on the different solubility of boron and phosphorus in gold is proposed to explain their diverse effectiveness in retaining the wurtzite phase. The wurtzite nanowires present a direct transition at the Γ point at approximately 1.5 eV while the diamond ones have a predominant emission around 1.1 eV. The aforementioned results are intriguing for innovative solar cell devices.
doi_str_mv	10.1021/nl4028445
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source	American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects	Applied sciences Boron - chemistry Cross-disciplinary physics: materials science rheology Devices Diamonds Emission Energy Exact sciences and technology Fullerenes and related materials diamonds, graphite Gold - chemistry Humans Materials science Nanocrystalline materials Nanoscale materials and structures: fabrication and characterization Nanostructure Nanowires Nanowires - chemistry Natural energy Phosphorus - chemistry Photovoltaic conversion Physics Quantum wires Silicon Silicon - chemistry Solar cells. Photoelectrochemical cells Solar Energy Solubility Specific materials Wurtzite
title	Preparing the Way for Doping Wurtzite Silicon Nanowires while Retaining the Phase
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