High performance ultrafiltration membrane composed of PVDF blended with its derivative copolymer PVDF-g-PEGMA

• Published in: Journal of membrane science 2013-10, Vol.445, p.66-75
• Main Authors: Liu, Baicang, Chen, Chen, Li, Tong, Crittenden, John, Chen, Yongsheng
• Format: Article
• Language: English
• Subjects: Amphiphilic copolymer; Applied sciences; artificial membranes; Atom transfer radical polymerization; Atomic force microscopy; Backbone; calcium chloride; calcium hydroxide; Chemistry; Colloidal state and disperse state; composite polymers; contact angle; Defect-free membrane; Exact sciences and technology; Exchange resins and membranes; Forms of application and semi-finished materials; General and physical chemistry; Graft copolymers; humic acids; Membranes; Poly(vinylidene fluoride) (PVDF); Polymer industry, paints, wood; polymerization; Polyvinylidene fluorides; Scanning electron microscopy; sodium alginate; solvents; Technology of polymers; Ultrafiltration; Ultrafiltration membrane; water potential; water treatment; X-ray photoelectron spectroscopy
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2013.05.043

Amphiphilic graft copolymers were fabricated from a poly(vinylidene fluoride) (PVDF) backbone that was grafted with poly(ethylene glycol) methyl ether methacrylate (PEGMA) (PVDF-g-PEGMA) using atom transfer radical polymerization (ATRP) method. An intriguing membrane of periodic pillar-like or sphere structures was formed using PVDF/PVDF-g-PEGMA block copolymer mixtures that were dissolved in suitable solvents. X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), atomic force microscopy (AFM), contact angle measurement, and flux performance tests were conducted to determine the membrane characteristics. The results show that the defect-free high performance ultrafiltration membrane can be fabricated by adding 10wt% or 15wt% PVDF-g-PEGMA to the PVDF backbone material using the phase inversion method. The permeate fluxes of the fabricated membrane with 10wt% and 15wt% PVDF534K-g-PEGMA are 5110 (L/m2hbar) and 5170 (L/m2hbar), respectively, for deionized water under 0.07MPa. The TOC (sodium alginate) removal efficiencies of PVDF membranes with 10wt%, and 15wt% PVDF534K-g-PEGMA are 90.97%, and 87.19%, respectively. Furthermore, the removals of Suwannee River humic acid that contained 2mM CaCl2 and 10mM Ca(OH)2 for the PVDF membrane with 10wt% PVDF534K-g-PEGMA are 72.11% and 77.69%, respectively. This defect-free high-performance membranes show good potential for water treatment applications. •Defect-free high performance membrane was formed by blending PVDF/PVDF-g-PEGMA.•An intriguing membrane of periodic pillar-like structures was presented.•The fabricated membranes exhibit ~200nm diameter spheres.•High flux of 5170 (L/m2hbar) under low transmembrane pressure (0.07MPa).•High removal efficiencies of SRHA (over 72% with calcium) and SA (over 87%).