Spectroscopic and Crystal Field Consequences of Fluoride Binding by [YbDTMA] super(3+) in Aqueous Solution

YbDTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [YbDTMAF] super(2+) and [YbDTMAOH sub(2)] super(3+) are in slow exchange on the relevant NMR timescale (

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2015-09, Vol.54 (37), p.10783-10786
Main Authors: Blackburn, Octavia A, Chilton, Nicholas F, Keller, Katharina, Tait, Claudia E, Myers, William K, McInnes, Eric JL, Kenwright, Alan M, Beer, Paul D, Timmel, Christiane R, Faulkner, Stephen
Format: Article
Language:English
Subjects:
Aqueous solutions
Binding
Fluorides
Ground state
Ligands
Magnetic anisotropy
Nuclear magnetic resonance
Spectra
Online Access:Get full text
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Description
Summary:YbDTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [YbDTMAF] super(2+) and [YbDTMAOH sub(2)] super(3+) are in slow exchange on the relevant NMR timescale (
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201503421