Picosecond Pulse Radiolysis Study of Dynamics of Solvation of Electron and Fluorenone Anion in Primary Alcohols

We have studied the dynamics of solvation of electron injected directly into primary alcohols as well as that of fluorenone anion using pulse radiolysis technique with the time resolution of about 15 ps. Unlike in the previous reports, we observe nonexponential dynamics of both electron and anion so...

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Bibliographic Details
Published in:The journal of physical chemistry. B 2014-01, Vol.118 (1), p.287-296
Main Authors: Palit, Dipak K, Torche, Fayçal, Marignier, Jean-Louis
Format: Article
Language:English
Subjects:
Alcohols
Anions
Company structure
Dynamics
Hydrogen bonds
Networks
Solvation
Solvents
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Summary:We have studied the dynamics of solvation of electron injected directly into primary alcohols as well as that of fluorenone anion using pulse radiolysis technique with the time resolution of about 15 ps. Unlike in the previous reports, we observe nonexponential dynamics of both electron and anion solvation. While the ultrafast component, τ1 (
ISSN:1520-6106
1520-5207
DOI:10.1021/jp410883j