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Electron Conductive and Proton Permeable Vertically Aligned Carbon Nanotube Membranes
We report the fabrication of membranes hundreds of micrometers thick that demonstrate efficient electron conduction and proton transport through vertically aligned arrays of multiwalled carbon nanotubes (NTs) impregnated by epoxy. Electrical transport was Ohmic with a conductivity of 495 mS cm–1. Pr...
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| Published in: | Nano letters 2014-04, Vol.14 (4), p.1728-1733 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-a444t-8c2e4c818bdc99e793f7ac402d07eb9815e49a62a58bb89577b99327e558a3913 |
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| cites | cdi_FETCH-LOGICAL-a444t-8c2e4c818bdc99e793f7ac402d07eb9815e49a62a58bb89577b99327e558a3913 |
| container_end_page | 1733 |
| container_issue | 4 |
| container_start_page | 1728 |
| container_title | Nano letters |
| container_volume | 14 |
| creator | Pilgrim, Gregory A Leadbetter, Joanne W Qiu, Fen Siitonen, Anni J Pilgrim, Steven M Krauss, Todd D |
| description | We report the fabrication of membranes hundreds of micrometers thick that demonstrate efficient electron conduction and proton transport through vertically aligned arrays of multiwalled carbon nanotubes (NTs) impregnated by epoxy. Electrical transport was Ohmic with a conductivity of 495 mS cm–1. Protons traversed the membrane through the NT bore with a current of 5.84 × 10–6 A. Good electron and proton transport, chemical robustness, and simple fabrication suggest NT membranes have potential in artificial photosynthesis applications. |
| doi_str_mv | 10.1021/nl403696y |
| format | article |
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Electrical transport was Ohmic with a conductivity of 495 mS cm–1. Protons traversed the membrane through the NT bore with a current of 5.84 × 10–6 A. Good electron and proton transport, chemical robustness, and simple fabrication suggest NT membranes have potential in artificial photosynthesis applications.</description><subject>Alignment</subject><subject>Arrays</subject><subject>Carbon nanotubes</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</subject><subject>Electronic transport in multilayers, nanoscale materials and structures</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Membranes</subject><subject>Nanocrystalline materials</subject><subject>Nanoscale materials and structures: fabrication and characterization</subject><subject>Nanotubes</subject><subject>New technology</subject><subject>Physics</subject><subject>Resistivity</subject><subject>Robustness</subject><subject>Transport</subject><issn>1530-6984</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqF0E1LwzAYwPEgipvTg19AehH0MM1rmxxHmS_gyw7Oa0nSZ9KRtjNphX17I5vbRfCUh_DjSfgjdE7wDcGU3DaOY5aqdH2AhkQwPE6Vooe7WfIBOglhiTFWTOBjNKBcpFymdIjmUwe2822T5G1T9rarviDRTZnMfNvF2xn4GrRxkLyD7yqrnVsnE1d9NFAmufYmmhfdtF1vIHmG2njdQDhFRwvtApxtzxGa303f8ofx0-v9Yz55GmvOeTeWlgK3kkhTWqUgU2yRacsxLXEGRkkigCudUi2kMVKJLDNKMZqBEFIzRdgIXW32rnz72UPoiroKFpyLn2j7UJAspVhwxen_VBDOGSNSRHq9oda3IXhYFCtf1dqvC4KLn-DFLni0F9u1vamh3MnfwhFcboEOsd4i9rFV2DvJUymE2DttQ7Fse9_EcH88-A1j65Mc</recordid><startdate>20140409</startdate><enddate>20140409</enddate><creator>Pilgrim, Gregory A</creator><creator>Leadbetter, Joanne W</creator><creator>Qiu, Fen</creator><creator>Siitonen, Anni J</creator><creator>Pilgrim, Steven M</creator><creator>Krauss, Todd D</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140409</creationdate><title>Electron Conductive and Proton Permeable Vertically Aligned Carbon Nanotube Membranes</title><author>Pilgrim, Gregory A ; 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Electrical transport was Ohmic with a conductivity of 495 mS cm–1. Protons traversed the membrane through the NT bore with a current of 5.84 × 10–6 A. Good electron and proton transport, chemical robustness, and simple fabrication suggest NT membranes have potential in artificial photosynthesis applications.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>24564862</pmid><doi>10.1021/nl403696y</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1530-6984 |
| ispartof | Nano letters, 2014-04, Vol.14 (4), p.1728-1733 |
| issn | 1530-6984 1530-6992 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1762054942 |
| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| subjects | Alignment Arrays Carbon nanotubes Condensed matter: electronic structure, electrical, magnetic, and optical properties Cross-disciplinary physics: materials science rheology Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures Electronic transport in multilayers, nanoscale materials and structures Exact sciences and technology Materials science Membranes Nanocrystalline materials Nanoscale materials and structures: fabrication and characterization Nanotubes New technology Physics Resistivity Robustness Transport |
| title | Electron Conductive and Proton Permeable Vertically Aligned Carbon Nanotube Membranes |
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