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An unprecedented organic-inorganic hybrid material with an I super(3)O super(3) framework based on cadmium hydroxide and in situ generated 1H-tetrazolate-5-acetic acid

Herein, we report a novel high-dimensional I super(3)O super(3) organic-inorganic hybrid framework, namely [Cd sub(3)(OH) sub(2)(tza) sub(2)] sub(n) (1) (H sub(2)tza = 1H-tetrazolate-5-acetic acid), where a rare pure ths inorganic connectivity of Cd-O sub(hydroxyl) is observed. Meanwhile, 1 displays...

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Bibliographic Details
Published in:CrystEngComm 2015-09, Vol.17 (39), p.7473-7476
Main Authors: Wu, Mei-Feng, Shen, Ting-Ting, He, Shuai, Wu, Ke-Qin, Wang, Shuai-Hua, Liu, Zhi-Fa, Zheng, Fa-Kun, Guo, Guo-Cong
Format: Article
Language:English
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Summary:Herein, we report a novel high-dimensional I super(3)O super(3) organic-inorganic hybrid framework, namely [Cd sub(3)(OH) sub(2)(tza) sub(2)] sub(n) (1) (H sub(2)tza = 1H-tetrazolate-5-acetic acid), where a rare pure ths inorganic connectivity of Cd-O sub(hydroxyl) is observed. Meanwhile, 1 displays blue emission and high thermal stability up to 370 degree C.
ISSN:1466-8033
DOI:10.1039/c5ce01347j