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An unprecedented organic-inorganic hybrid material with an I super(3)O super(3) framework based on cadmium hydroxide and in situ generated 1H-tetrazolate-5-acetic acid
Herein, we report a novel high-dimensional I super(3)O super(3) organic-inorganic hybrid framework, namely [Cd sub(3)(OH) sub(2)(tza) sub(2)] sub(n) (1) (H sub(2)tza = 1H-tetrazolate-5-acetic acid), where a rare pure ths inorganic connectivity of Cd-O sub(hydroxyl) is observed. Meanwhile, 1 displays...
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Published in: | CrystEngComm 2015-09, Vol.17 (39), p.7473-7476 |
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Main Authors: | , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | Herein, we report a novel high-dimensional I super(3)O super(3) organic-inorganic hybrid framework, namely [Cd sub(3)(OH) sub(2)(tza) sub(2)] sub(n) (1) (H sub(2)tza = 1H-tetrazolate-5-acetic acid), where a rare pure ths inorganic connectivity of Cd-O sub(hydroxyl) is observed. Meanwhile, 1 displays blue emission and high thermal stability up to 370 degree C. |
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ISSN: | 1466-8033 |
DOI: | 10.1039/c5ce01347j |