Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(III) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-ind...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (84), p.15358-15361
Main Authors: Wang, Long-Fei, Qiu, Jiang-Zhen, Liu, Jun-Liang, Chen, Yan-Cong, Jia, Jian-Hua, Jover, Jesús, Ruiz, Eliseo, Tong, Ming-Liang
Format: Article
Language:English
Subjects:
Cycloaddition
Irradiation
Modulation
Transformations
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(III) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-induced slow relaxation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc07073b