An approach towards expanding the scope of masked o-benzoquinone dimers to generate diverse compound libraries

In this report, a simple and rapid approach for the synthesis of masked o -benzoquinone (MOB) heterodimers is presented. Appropriately substituted 2-methoxyphenols were converted to MOB homodimers which were then transformed to MOB heterodimers utilizing either vinylic substitution ( via addition-el...

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Bibliographic Details
Published in:RSC advances 2015-01, Vol.5 (37), p.29391-29396
Main Authors: Chittimalla, Santhosh Kumar, Laxmi, Shoba, Ming Liing, Amerlyn Chong, Kai Jun, Jerald Lam, Kuppusamy, Rajesh, Putturu, Sireesha, Bandi, Chennakesavulu
Format: Article
Language:English
Subjects:
Dimers
Libraries
Metalorganic compounds
Synthesis
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Summary:In this report, a simple and rapid approach for the synthesis of masked o -benzoquinone (MOB) heterodimers is presented. Appropriately substituted 2-methoxyphenols were converted to MOB homodimers which were then transformed to MOB heterodimers utilizing either vinylic substitution ( via addition-elimination) reaction protocol or organometallic reaction procedures.
ISSN:2046-2069
2046-2069
DOI:10.1039/C5RA03627E