Core–shell system based on titanium dioxide with elevated value of dielectric permittivity: Synthesis and characterization

• Published in: Synthetic metals 2015-11, Vol.209, p.150-157
• Main Authors: Krysiak, Ewa, Wypych-Puszkarz, Aleksandra, Krysiak, Kamil, Nowaczyk, Grzegorz, Makrocka-Rydzyk, Monika, Jurga, Stefan, Ulanski, Jacek
• Format: Article
• Language: English
• Subjects: Atom transfer radical polymerization (ATRP); Ceramics; Core–shell structure; Dielectric materials; Dielectrics; Grafting; Nanocomposites; Nanoparticles; Permittivity; Polymerization; Radicals; Titanium dioxide
• ISSN: 0379-6779; 1879-3290
• DOI: 10.1016/j.synthmet.2015.06.028

[Display omitted] •Atom transfer radical polymerization (ATRP) from titanium dioxide surface.•FTIR and NMR analyses confirmed a presence of polymer chain grafted from nanoparticles surface.•TGA analysis shows 21% weight loss polymer from core–shell nanoparticles.•Dielectric measurements exhibit that core–shell nanocomposite has elevated value of dielectric permittivity and low loss tangent.•Long-lasting dispersion stability of modified TiO2 in dichloromethane. In this work we report a reproducible and efficient method of surface modification of titania nanoparticles (rutile) via reversible-deactivation radical polymerization. Herein, we graft poly(di(ethylene glycol) methyl ether methacrylate) from the surface of TiO2 in an amount of 21wt% within the reaction time of 3h 15min. The amount of grafted polymer was assessed by Thermogravimetric Analysis and it is one of the highest reported till now for this ceramic nanoparticles by atom transfer radical polymerization. The properties of inorganic-organic, i.e. core–shell material, as well as of pristine TiO2 and neat polymer were examined by Infrared and Dielectric Spectroscopies. The shape of the nanoparticles and the thickness of the polymer coating shell were investigated by means of High Resolution Transmission Electron Microscopy. The obtained nanocomposite exhibits dielectric permittivity ϵ′=18 and loss tangent around 1×10−2 at 20°C. The described method allows controlling a length and chemical structure of the grafted polymer from ceramic core, thus to tailor a physical properties of nanoparticles and of nanocomposites.