Temporal–spatial reconstruction of the early Frasnian (Late Devonian) anoxia in NW Africa: new field data from the Ahnet Basin (Algeria)

• Published in: Sedimentary geology 2004-01, Vol.163 (3), p.237-264
• Main Authors: Lüning, S., Wendt, J., Belka, Z., Kaufmann, B.
• Format: Article
• Language: English
• Subjects: Algeria; Black shale; Frasnian; Gamma-ray; Source rock; Upper Devonian
• ISSN: 0037-0738; 1879-0968
• DOI: 10.1016/S0037-0738(03)00210-0

Anoxic conditions were widespread in NW Africa during the early Frasnian (Late Devonian) that resulted in deposition of organic-rich shales and limestones with total organic carbon (TOC) values of up to 14%. Organic richness and thickness of these sediments vary laterally, and organic-rich vs. organic-poor facies boundaries are likely to have been diachronous. A precise temporal–spatial reconstruction of this anoxic phase in NW Africa is complicated because the organic matter in outcrops is largely oxidised and biostratigraphic resolution in boreholes is generally low due to the lack of recoverable conodonts. This contribution is based on eight outcrop sections at the margin of the central Algerian Ahnet Basin, where detailed spectral gamma-ray measurements were carried out using a handheld instrument. The pre-weathering organic richness in Frasnian outcrop sections is approximated using the characteristic uranium enrichment in the anoxic facies that, based on well studies, is positively correlated with the total organic carbon content. Conodont biostratigraphic results from these sections suggest that the uranium-enriched interval (the anoxic interval) at the basin margin is most common in the basal Frasnian conodont Biozones 1–2, confirming previous results from the Anti Atlas in Morocco. In three of the eight localities studied the basal Frasnian has not been deposited and the Frasnian here commences with distinctly younger uranium-enriched intervals, including Zones 4–11. Well data from the eastern Algerian Berkine Basin is interpreted to indicate a significantly longer anoxic phase there. Million-year-scale diachroneities of the Frasnian anoxia, therefore, clearly exist across the North Africa shelf. It is assumed that the palaeorelief might have been a major factor in controlling the onset, duration, and intensity of anoxia in the region.