Novel method for synthesis of silver nanoparticles and their application on wool

• Published in: Applied surface science 2015-08, Vol.346, p.477-483
• Main Authors: Boroumand, Majid Nasiri, Montazer, Majid, Simon, Frank, Liesiene, Jolanta, Šaponjic, Zoran, Dutschk, Victoria
• Format: Article
• Language: English
• Subjects: Antibacterial; Bacteria; Dyes; Fabrics; Nanoparticles; Natural dye; Pomegranate; Reduction; Silver; Silver nanoparticle; Synthesis; Wool
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2015.04.047

Tentative mechanism for reduction of Ag+ by polyphenols having two hydroxy groups in ortho-position – the use of silver nanoparticles and an aqueous solution of extracted dye from Pomegranate peel as a reducing agent for synthesis silver nanoparticles from silver nitrate. •A new method for the synthesis of silver nanoparticles suitable to impart antibacterial properties of wool fabric proposed.•Silver nanopartilces were synthesized by a biochemical reduction method.•An aqueous solution of extracted dye from Pomegranate peel was used as a reducing agent for synthesis of silver nanoparticles from silver nitrate. In this study, a new method for the synthesis of silver nanoparticles (AgNPs) suitable to impart antibacterial properties of wool fabric is proposed. AgNPs were synthesized by a biochemical reduction method. An aqueous solution of extracted dye from Pomegranate peel was used as a reducing agent for the synthesis of AgNPs from silver nitrate. The ratio of dye to silver nitrate concentration (RDye/Ag=[Dye]/[AgNO3]) is the influencing factor in the synthesis of silver nanoparticles. The nanoparticles formation was followed by UV/Vis absorption spectroscopy. The size and shape of AgNPs were studied by transmission electron microscopy (TEM). The size distribution and Zetapotential of nanoparticles were evaluated using diffraction light scattering (DLS) measurements. The antibacterial potential of biosynthesized silver nanoparticles against Escherichia coli (E. coli) was examined qualitatively and quantitatively. Kinetic analysis of the bacteria reduction using AgNPs synthesized in different way was performed. AgNPs were applied on wool fabrics by exhaustion. The changes in surface morphology of wool fibers after AgNPs loading were studied using scanning electron microscopy (SEM). The amounts of silver deposited on wool fabrics at different pH and temperature were compared applying energy-dispersive X-ray spectroscopy (EDX). AgNPs loaded fabrics showed excellent antibacterial efficiency even after five washing cycles. To investigate the nature of interaction and bonding between the AgNPs and the wool substrate XPS measurements were performed.